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91.
Few investigations have addressed the interaction between soil surface water regimes and raindrop impact on nutrient losses, especially under artesian seepage condition. A simulation study was conducted to examine the effects on nitrogen and phosphorus losses. Four soil surface water regimes were designed: free drainage, saturation with rainfall, artesian seepage without rainfall, and artesian seepage with rainfall. These water regimes were subjected to two surface treatments: with and without raindrop impact through placing nylon net over soil pan. The results showed saturation and seepage with rainfall conditions induced greater soil loss and nutrient losses than free drainage condition. Nutrient concentrations in runoff from artesian seepage without rainfall condition were 7.3–228.7 times those from free drainage condition. Nutrient losses by runoff from saturation and seepage with rainfall conditions increased by factors of 1.30–9.38 and 2.81–40.11 times, and the corresponding losses with eroded sediment by 1.37–7.67 and 1.75–9.0 times, respectively, relative to those from free drainage condition. Regardless of different soil surface water regimes, raindrop impact increased 20.90–94.0 % nutrient losses with eroded sediment by promoting soil loss, but it only significantly enhanced nutrient transport to runoff under free drainage condition.  相似文献   
92.
The European Alps are very sensitive and vulnerable to climate change. Recent improvements in Alpine glacier length records and climate reconstructions from annually laminated sediments of Alpine Lake Silvaplana give the opportunity to investigate the relationship between these two data sets of Alpine climate. Two different time frames are considered: the last 500–1000 years as well as the last 7400 years. First, we found good agreement between the two different climate archives during the past millennium: mass accumulation rates and biogenic silica concentration are largely in phase with the glacier length changes of Mer de Glace and Unterer Grindelwaldgletscher, and with the records of glacier length of Grosser Aletschgletscher and Gornergletscher. Secondly, the records are compared with temporally highly resolved data of solar activity. The Sun has had a major impact on the Alpine climate variations in the long term, i.e. several centuries to millennia. Solar activity varies with the Hallstatt periodicity of about 2000 years. Hallstatt minima are identified around 500, 2500 and 5000 a. Around these times grand solar minima (such as the Maunder Minimum) occurred in clusters coinciding with colder Alpine climate expressed by glacier advances. During the Hallstatt maxima around 0, 2000 and 4500 a, the Alpine glaciers generally retreated, indicating a warmer climate. This is supported by archaeological findings at Schnidejoch, a transalpine pass in Switzerland that was only accessible when glaciers had retreated. On shorter timescales, however, the influence of the Sun cannot be as easily detected in Alpine climate change, indicating that in addition to solar forcing, volcanic influence and internal climate variations have played an important role. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   
93.
As a result of aquaculture activities Pacific oysters Crassostrea gigas (Thunberg, 1793) have invaded the European Wadden Sea. Using a variable noncoding mitochondrial marker, we show that the invaded range is the result of two independent invasions. Haplotype frequencies point towards two separate groups, one in the southern and the other in the northern Wadden Sea. We found virtually no genetic differentiation throughout the southern range and the putative source from British Columbia, Canada, suggesting that the Southern region can be considered as a closed population. In the North, mismatch distributions, haplotype ordination and isolation-by-distance analysis suggest a stronger, persistent impact of aquaculture on invasive populations. Due to the ongoing supply of new genetic material from hatchery production the northern invasive populations can therefore be considered as an open population highlighting the importance of aquaculture practice on the genetics of this keystone invader in the Wadden Sea.  相似文献   
94.
95.
Weathering of volcanic tuff rocks caused by moisture expansion   总被引:1,自引:1,他引:0  
Moisture expansion in natural building stones is considered one of the most important factors affecting their weathering and deterioration. The processes that may be responsible for the expansion under determinate relative humidity (hygric dilatation) and water-saturated conditions (hydric dilatation) are generally attributed to the presence of swellable clay minerals. In contrast to this assumption, our investigations show that moisture expansion also takes place in volcanic tuff building stones almost free from clay minerals. To provide a deeper understanding of the processes, swelling and deterioration were performed on 14 volcanic tuffs used as important building stones of different ages, compositions and weathering stages from Mexico, Germany and Hungary. The investigations undertaken include extensive chemical, petrophysical and fabric analyses. The samples show a wide range of effective porosity, microporosity, capillary water absorption, moisture expansion, and CEC values. High moisture expansion does not seem to depend on clay mineral content alone. We also observed that there is no significant effect on dilatation if clay minerals are present but only form a thin coat on the outer shell of bigger pores. Moreover, we identified a correlation between microporosity, average pore radius and moisture expansion. The investigations highlight the fact that moisture expansion cannot only be attributed to swellable clay minerals, and suggest that the presence and accumulation of micropores and their average radius and distribution play an important role for non-clay associated swelling intensity, which can most probably be attributed to the disjoining pressure.  相似文献   
96.
In order to address the growth of crystals in veins, a multiphase-field model is used to capture the dynamics of crystals precipitating from a super-saturated solution. To gain a detailed understanding of the polycrystal growth phenomena in veins, we investigate the influence of various boundary conditions on crystal growth. In particular, we analyze the formation of vein microstructures resulting from the free growth of crystals as well as crack-sealing processes. We define the crystal symmetry by considering the anisotropy in surface energy to simulate crystals with flat facets and sharp corners. The resulting growth competition of crystals with different orientations is studied to deduce a consistent orientation selection rule in the free-growth regime. Using crack-sealing simulations, we correlate the grain boundary tracking behavior depending on the relative rate of crack opening, opening trajectory, initial grain size, and wall roughness. Further, we illustrate how these parameters induce the microstructural transition between blocky (crystals growing anisotropically) to fibrous morphology (isotropic) and formation of grain boundaries. The phase-field simulations of crystals in the free-growth regime (in 2D and 3D) indicate that the growth or consumption of a crystal is dependent on the orientation difference with neighboring crystals. The crack-sealing simulation results (in 2D and 3D) reveal that crystals grow isotropically and grain boundaries track the opening trajectory if the wall roughness is high, opening increments are small, and crystals touch the wall before the next crack increment starts. Further, we find that within the complete crack-seal regime, anisotropy in surface energy results in the formation of curved/oscillating grain boundaries (instead of straight) when the crack-opening velocity is increased and wall roughness is not sufficiently high. Additionally, the overall capability of phase-field method to simulate large-scale polycrystal growth in veins (in 3D) is demonstrated enumerating the main advantages of adopting the novel approach.  相似文献   
97.
We present the results of a spectroscopic multisite campaign for the β Cephei star 12 (DD) Lacertae. Our study is based on more than thousand high-resolution high S/N spectra gathered with eight different telescopes in a time span of 11 months. In addition, we make use of numerous archival spectroscopic measurements. We confirm 10 independent frequencies recently discovered from photometry, as well as harmonics and combination frequencies. In particular, the slowly pulsating B-stars (SPB)-like g -mode with frequency 0.3428 d−1 reported before is detected in our spectroscopy. We identify the four main modes as  (ℓ1, m 1) = (1, 1), (ℓ2, m 2) = (0, 0), (ℓ3, m 3) = (1, 0)  and  (ℓ4, m 4) = (2, 1)  for   f 1= 5.178 964 d−1, f 2= 5.334 224 d−1, f 3= 5.066 316 d−1  and   f 4= 5.490 133 d−1  , respectively. Our seismic modelling shows that f 2 is likely the radial first overtone and that the core overshooting parameter  αov  is lower than 0.4 local pressure scale heights.  相似文献   
98.
The local structural heterogeneity and energetic properties of 22 natural Mg–Fe cordierites, ideal formula (Mg,Fe)2Al4Si5O18·x(H2O,CO2), were investigated at length scales given by powder infrared spectroscopy (IR) and also by published electronic absorption spectra. The studied samples have iron mole fractions from XFe = 0.06 to 0.82 and cover most of the Mg–Fe cordierite binary. Variations in wavenumbers and line widths of the IR bands were determined as a function of composition. Most modes shift linearly to lower wavenumbers with increasing XFe, except those at high wavenumbers located between 900 and 1,200 cm-1. They are vibrations that have a large internal (Si,Al)O4 character and are not greatly affected by Mg–Fe exchange on the octahedral site. The lower wavenumber modes can be best characterized as lattice vibrations having mixed character. The systematics of the wavenumber shifts suggest small continuous variations in the "average" cordierite structure with Mg–Fe exchange and are consistent with an ideal volume of mixing, Vmix= 0, behavior (Boberski and Schreyer 1990). IR line broadening was measured using the autocorrelation function for three wavenumber regions in order to determine the range of structural heterogeneity between roughly 2 and 100 Å (0.2–10.0 nm) in the solid solution. In order to do this, an empirical correction was first made to account for the effect that small amounts of channel Na have on the phonon systematics. The results show that between 1,200 and 540 cm-1 the line widths of the IR bands broaden slightly and linearly with increasing XFe. Between 350 and 125 cm-1 nonlinear behavior was observed and it may be related to dynamic effects. These results suggest minimal excess elastic enthalpies of mixing for Mg–Fe cordierite solid solutions. Channel Na should affect measurably the thermodynamic properties of natural cordierites as evidenced by variations in the IR spectra of Na-containing samples. Occluded H2O (Class I) and CO2 should have little interaction with the framework and can be considered nearly "free" molecules. They should not give rise to measurable structural heterogeneity in the framework. The contribution of the crystal field stabilization energy (CFSE) of octahedral Fe2+ to the energetics of Mg–Fe cordierites was also investigated using published electronic absorption spectra (Khomenko et al. 2001). Two bands are observed between 8,000 and 10,500 cm-1 and they represent electronic dd-excitations of octahedral Fe2+ derived from the 5T2g 5Eg transition. They shift to higher wavenumbers with increasing XMg in cordierite. An analysis gives slightly asymmetric excess -CFSE across the Mg–Fe cordierite join with a maximum of about –550 J/mole towards iron-rich compositions.Editorial responsibility: J. Hoefs  相似文献   
99.
This contribution investigates the nature of turbulent kinetic energy (TKE) in a steep and narrow Alpine valley under fair-weather summertime conditions. The Riviera Valley in southern Switzerland was chosen for a detailed case study, in which the evaluation of aircraft data (obtained from the MAP-Riviera field campaign) is combined with the application of high-resolution (350-m horizontal grid spacing) large-eddy simulations using the numerical model ARPS. The simulations verify what has already been observed on the basis of measurements: TKE profiles scale surprisingly well if the convective velocity scale w * is obtained from the sun-exposed eastern slope rather than from the surface directly beneath the profiles considered. ARPS is then used to evaluate the TKE-budget equation, showing that, despite sunny conditions, wind shear is the dominant production mechanism. Therefore, the surface heat flux (and thus w *) on the eastern slope does not determine the TKE evolution directly but rather, as we believe, indirectly via the interaction of thermally-driven cross-valley and along-valley flows. Excellent correlation between w * and the up-valley wind speed solidifies this hypothesis.  相似文献   
100.
The severity and frequency of sixteenth-century floods of the Rhine, the Main, the middle and upper Elbe with its tributaries, rivers of northern and central Italy, the Garonne and rivers in Catalonia and Andalusia are analyzed using documentary evidence. The basic topographical and hydrological characteristics of the rivers investigated as well as the synoptic causes of their flooding during the instrumental period are presented. Different examples of modifications of the run-off process due to anthropogenic activity are discussed. Prevalence in flood occurrence during the second half of the sixteenth century in comparison to the first half is typical for central European and Andalusian rivers (mainly in the 1560s and 1590s) and agrees with the evolution of precipitation patterns. On the other hand, Italian and Catalonian rivers, in part, had a higher occurrence of floods during the first half of the century. Changes in the flooding seasons in both halves of the century are not unambiguous. Results of an analysis on a broader European scale show floods to be a random natural phenomena with limited areal extent defined by the spatial influence of forcing meteorological factors (continuous heavy rains, sudden melting of thick snow cover, etc.). Despite some limitations of documentary evidence, series of reconstructed historical floods are valuable sources of proxy data which can be utilized for the study of the flooding fluctuations in the pre-instrumental period.  相似文献   
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